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Emerald bolt tips are attached to the tips of Mithril bolts, and can then be enchanted. Once Emerald bolt tips have been attached, the mithril bolts become Emerald bolts.
Emerald bolt tips can be created through the Fletching skill. A player must have a Fletching level of 58 and take a cut Emerald and use a chisel with it to make 12 Emerald bolt tips and earn 5.5 exp.